42 C.F.R. Subpart L—Chemical Cartridge Respirators
Title 42 - Public Health
(a) Chemical cartridge respirators including all completely assembled respirators which are designed for use as respiratory protection during entry into or escape from atmospheres not immediately dangerous to life and health, are described according to the specific gases or vapors against which they are designed to provide respiratory protection, as follows: (b) Chemical cartridge respirators for respiratory protection against gases or vapors, which are not specifically listed with their maximum use concentration, may be approved if the applicant submits a request for such approval, in writing, to the Institute. The Institute shall consider each such application and accept or reject the application after a review of the effects on the wearer's health and safety and in the light of any field experience in use of chemical cartridge respirators as protection against such hazards. (a) Each chemical cartridge respirator described in §84.190 shall, where its design requires, contain the following component parts: (1) Facepiece, mouthpiece, and noseclip, hood, or helmet; (2) Cartridge; (3) Cartridge with filter; (4) Harness; (5) Breathing tube; and (6) Attached blower. (b) The components of each chemical cartridge respirator shall meet the minimum construction requirements set forth in subpart G of this part. Where two or more cartridges are used in parallel, their resistance to airflow shall be essentially equal. The color and markings of all cartridges or labels shall conform with the requirements of the American National Standards Institute, American National Standard for Identification of Air-Purifying Respirator Canisters and Cartridges, ANSI K13.1–1973. ANSI K13.1 is incorporated by reference and has been approved by the Director of the Federal Register in accordance with 5 U.S.C. 552(a) and 1 CFR part 51. Copies may be obtained from American National Standards Institute, Inc., 1430 Broadway, New York, NY 10018. Copies may be inspected at the NIOSH, Certification and Quality Assurance Branch, 1095 Willowdale Road, Morgantown, WV 26505–2888, or at the National Archives and Records Administration (NARA). For information on the availability of this material at NARA, call 202–741–6030, or go to: http://www.archives.gov/federal_register/code_of_federal_regulations/ibr_locations.php. (a) Particulate matter filters used in conjunction with a chemical cartridge shall be located on the inlet side of the cartridge. (b) Filters shall be incorporated in or firmly attached to the cartridge and each filter assembly shall, where applicable, be designed to permit its easy removal from and replacement on the cartridge. Flexible breathing tubes used in conjunction with respirators shall be designed and constructed to prevent: (a) Restriction of free head movement; (b) Disturbance of the fit of facepieces, mouthpieces, hoods, or helmets; (c) Interference with the wearer's activities; and (d) Shutoff of airflow due to kinking, or from chin or arm pressure. (a) Each respirator shall, where necessary, be equipped with a suitable harness designed and constructed to hold the components of the respirator in position against the wearer's body. (b) Harnesses shall be designed and constructed to permit easy removal and replacement of respirator parts and, where applicable, provide for holding a full facepiece in the ready position when not in use. Respirators shall be equipped with a substantial, durable container bearing markings which show the applicant's name, the type and commercial designation of the respirator it contains and all appropriate approval labels. (a) Half-mask facepieces and full facepieces shall be designed and constructed to fit persons with various facial shapes and sizes either: (1) By providing more than one facepiece size; or (2) By providing one facepiece size which will fit varying facial shapes and sizes. (b) Hoods and helmets shall be designed and constructed to fit persons with various head sizes, provide for the optional use of corrective spectacles or lenses, and insure against any restriction of movement by the wearer. (c) Mouthpieces shall be equipped with noseclips which are securely attached to the mouthpiece or respirator and provide an airtight fit. (d) Full facepieces shall provide for optional use of corrective spectacles or lenses which shall not reduce the respiratory protective qualities of the respirator. (e) Facepieces, hoods, and helmets shall be designed to prevent eyepiece fogging. Facepieces, hoods, and helmets shall be designed and constructed to provide adequate vision which is not distorted by the eyepieces. (a) Inhalation and exhalation valves shall be provided where necessary and protected against distortion. (b) Inhalation valves shall be designed and constructed to prevent excessive exhaled air from entering cartridges or adversely affecting canisters. (c) Exhalation valves shall be— (1) Protected against damage and external influence; and (2) Designed and constructed to prevent inward leakage of contaminated air. (a)(1) Facepieces for chemical cartridge respirators other than single-use vinyl chloride shall be equipped with adjustable and replaceable head harnesses designed and constructed to provide adequate tension during use and an even distribution of pressure over the entire area in contact with the face. (2) Facepieces for single-use vinyl chloride respirators shall be equipped with adjustable head harnesses designed and constructed to provide adequate tension during use and an even distribution of pressure over the entire area in contact with the face. (b) Mouthpieces shall be equipped where applicable, with an adjustable and replaceable harness designed and constructed to hold the mouthpiece in place. Noise levels generated by the respirator will be measured inside the hood or helmet at maximum airflow obtainable and shall not exceed 80 dBA. (a) Resistance to airflow will be measured in the facepiece, mouthpiece, hood, or helmet of a chemical cartridge respirator mounted on a test fixture with air flowing at a continuous rate of 85 liters per minute, both before and after each test conducted in accordance with §§84.206 through 84.207. (b) The maximum allowable resistance requirements for chemical cartridge respirators are as follows: (a) Dry exhalation valves and valve seats will be subjected to a suction of 25 mm. water-column height while in a normal operating position. (b) Leakage between the valve and valve seat shall not exceed 30 milliliters per minute. (a) The complete chemical cartridge respirator will be fitted to the faces of persons having varying facial shapes and sizes. (b) Where the applicant specifies a facepiece size or sizes for the respirator together with the approximate measurement of faces they are designed to fit, the Institute will provide test subjects to suit such facial measurements. (c) Any chemical cartridge respirator part which must be removed to perform the facepiece or mouthpiece fit test shall be replaceable without special tools and without disturbing facepiece or mouthpiece fit. (d) The facepiece or mouthpiece fit test using the positive or negative pressure recommended by the applicant and described in his instructions will be used before each test. (e)(1) Each wearer will enter a chamber containing 100 p.p.m. isoamyl acetate vapor for half-mask facepieces, and 1,000 p.p.m. for full facepieces, mouthpieces, hoods, and helmets. (2) The facepiece or mouthpiece may be adjusted, if necessary, in the test chamber before starting the test. (3) Each wearer will remain in the chamber for 8 minutes while performing the following activities: (i) Two minutes, nodding and turning head; (ii) Two minutes, calisthenic arm movements; (iii) Two minutes, running in place; and (iv) Two minutes, pumping with a tire pump into a 28-liter (1 cubic-foot) container. (4) Each wearer shall not detect the odor of isoamyl-acetate vapor during the test. (a) Three respirators with cartridges containing, or having attached to them, filters for protection against particulates will be tested in accordance with the provisions of §84.207. (b) In addition to the test requirements set forth in paragraph (a) of this section, three such respirators will be tested, as appropriate, in accordance with the provisions of §§84.179 through 84.183; however, the maximum allowable resistance of complete particulate, and gas, vapor, or gas and vapor chemical cartridge respirators shall not exceed the maximum allowable limits set forth in §84.203. (a) Bench tests will be made on an apparatus that allows the test atmosphere at 50 ±5 percent relative humidity and room temperature, approximately 25 °C, to enter the cartridges continuously at predetermined concentrations and rates of flow, and that has means for determining the test life of the cartridges. (b) Where two cartridges are used in parallel on a chemical cartridge respirator, the bench test will be performed with the cartridges arranged in parallel, and the test requirements will apply to the combination rather than to the individual cartridges. (c) Three cartridges or pairs of cartridges will be removed from containers and tested as received from the applicant. (d) Two air purifying cartridges or pairs of cartridges will be equilibrated at room temperature by passing 25 percent relative humidity air through them at the flow rate of 25 liters per minute (l.p.m.) for 6 hours. (e) Two air purifying cartridges or pairs of cartridges will be equilibrated by passing 85 percent relative humidity air through them at the flow rate of 25 l.p.m. (f) All cartridges will be resealed, kept in an upright position, at room temperatures, and tested within 18 hours. (g) Cartridges will be tested and shall meet the minimum requirements set forth in Table 11 of this subpart.
Title 42: Public Health
PART 84—APPROVAL OF RESPIRATORY PROTECTIVE DEVICES
Subpart L—Chemical Cartridge Respirators
§ 84.190 Chemical cartridge respirators: description.
------------------------------------------------------------------------ Maximum use concentration, Type of chemical cartridge respirator \1\ parts per million------------------------------------------------------------------------Ammonia................................................. 300Chlorine................................................ 10Hydrogen chloride....................................... 50Methyl amine............................................ 100Organic vapor........................................... \2\ 1,000Sulfur dioxide.......................................... 50Vinyl chloride.......................................... 10------------------------------------------------------------------------\1\ Not for use against gases or vapors with poor warning properties (except where MSHA or Occupational Safety and Health Administration standards may permit such use for a specific gas or vapor) or those which generate high heats of reaction with sorbent material in the cartridge.\2\ Maximum use concentrations are lower for organic vapors which produce atmospheres immediately hazardous to life or health at concentrations equal to or lower than this concentration.
§ 84.191 Chemical cartridge respirators; required components.
§ 84.192 Cartridges in parallel; resistance requirements.
§ 84.193 Cartridges; color and markings; requirements.
§ 84.194 Filters used with chemical cartridges; location; replacement.
§ 84.195 Breathing tubes; minimum requirements.
§ 84.196 Harnesses; installation and construction; minimum requirements.
§ 84.197 Respirator containers; minimum requirements.
§ 84.198 Half-mask facepieces, full facepieces, mouthpieces, hoods, and helmets; fit; minimum requirements.
§ 84.199 Facepieces, hoods, and helmets; eyepieces; minimum requirements.
§ 84.200 Inhalation and exhalation valves; minimum requirements.
§ 84.201 Head harnesses; minimum requirements.
§ 84.202 Air velocity and noise levels; hoods and helmets; minimum requirements.
§ 84.203 Breathing resistance test; minimum requirements.
Maximum Resistance [Millimeter water column height]------------------------------------------------------------------------ Inhalation Type of chemical-cartridge -------------------------- Exhalation respirator Initial Final\1\------------------------------------------------------------------------Other than single-use vinyl chloride respirators: For gases, vapors, or gases 40 45 20 and vapors.................. For gases, vapors, or gases 50 70 20 and vapors, and particulatesSingle-use respirator with valves: For vinyl chloride........... 20 25 20 For vinyl chloride and 30 45 2 particulates................Single-use respirator without valves: For vinyl chloride........... 15 20 (\2\) For vinyl chloride and 25 40 (\2\) particulates................------------------------------------------------------------------------\1\ Measured at end of service life specified in Table 11 of this subpart.\2\ Same as inhalation.
§ 84.204 Exhalation valve leakage test; minimum requirements.
§ 84.205 Facepiece test; minimum requirements.
§ 84.206 Particulate tests; respirators with filters; minimum requirements; general.
§ 84.207 Bench tests; gas and vapor tests; minimum requirements; general.
Tables to Subpart L of Part 84
Tables 9-10 [Reserved] Table 11_Cartridge Bench Tests and Requirements [42 CFR part 84, subpart L]-------------------------------------------------------------------------------------------------------------------------------------------------------- Test atmosphere -------------------------------------- Flowrate Number of Penetration Minimum Cartridge Test condition Concentration (l.p.m.) tests \1\ life \2\ Gas or vapor (p.p.m.) (p.p.m.) (min.)--------------------------------------------------------------------------------------------------------------------------------------------------------Ammonia.............................. As received............ NH3 1000 64 3 50 50Ammonia.............................. Equilibrated........... NH3 1000 32 4 50 50Chlorine............................. As received............ Cl2 500 64 3 5 35Chlorine............................. Equilibrated........... Cl2 500 32 4 5 35Hydrogen chloride.................... As received............ HCl 500 64 3 5 50Hydrogen chloride.................... Equilibrated........... HCl 500 32 4 5 50Methylamine.......................... As received............ CH3 NH2 1000 64 3 10 25Methylamine.......................... Equilibrated........... CH3 NH2 1000 32 4 10 25Organic vapors....................... As received............ CCl4 1000 64 3 5 50Organic vapors....................... Equilibrated........... CCl4 1000 32 4 5 50Sulfur dioxide....................... As received............ SO2 500 64 3 5 30Sulfur dioxide....................... Equilibrated........... SO2 500 32 4 5 30--------------------------------------------------------------------------------------------------------------------------------------------------------\1\ Minimum life will be determined at the indicated penetration.\2\ Where a respirator is designed for respiratory protection against more than one type of gas or vapor, as for use in ammonia and in chlorine, the minimum life shall be one-half that shown for each type of gas or vapor. Where a respirator is designed for respiratory protection against more than one gas of a type, as for use in chlorine and sulfur dioxide, the stated minimal life shall apply.
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